Complejos metalosupramoleculares de Cu(I), Ag(I), Au(I), Pd(II) y Pt(II)síntesis, caracterización estructural y propiedades biológicas

  1. González Barcia, Luis MIguel
Dirigida por:
  1. Manuel R. Bermejo Patiño Director
  2. Ana María González Noya Codirectora
  3. Rosa Pedrido Castiñeiras Codirectora

Universidad de defensa: Universidade de Santiago de Compostela

Fecha de defensa: 20 de diciembre de 2019

Tribunal:
  1. Javier García Tojal Presidente/a
  2. M. Angeles Sanchez Gonzalez Secretaria
  3. M. Emilia Bertolo Pardo Vocal
Departamento:
  1. Departamento de Química Inorgánica

Tipo: Tesis

Resumen

In this thesis, metallosupramolecular compounds of Cu(I), Ag(I), Au(I), Pd(II) and Pt(II) have been developed from functionalized ligands with phosphines (Schiff bases, thiosemicarbazones and semicarbazones) which have allowed us to obtain valuable information for the comprehension of self-assembly processes in that kind of systems. In particular, the desulfurization process of a double cluster helicate derived from Ag(I) and thiosemicarbazone has been studied in detail. The great relevance of some of these metal ions at the biological level has allowed a preliminary evaluation of the potential complexes applications as possible metallodrugs.