Physical organic chemistry of transition metal carbene complexes. 10. Opposing effects of α-alkyl groups on the thermodynamic and kinetic acidities of (CO)5Cr = C(OMe)CHR'R''-type fischer carbene complexes in aqueous acetonitrile. Analogy to the nitroalkane anomaly

  1. Bernasconi, C.F.
  2. Sun, W.
  3. Garcia-Río, L.
  4. Yan, K.
  5. Kittredge, K.
Journal:
Journal of the American Chemical Society

ISSN: 0002-7863

Year of publication: 1997

Volume: 119

Issue: 24

Pages: 5583-5590

Type: Article

DOI: 10.1021/JA970193Z GOOGLE SCHOLAR