Physical organic chemistry of transition metal carbene complexes. 10. Opposing effects of α-alkyl groups on the thermodynamic and kinetic acidities of (CO)5Cr = C(OMe)CHR'R''-type fischer carbene complexes in aqueous acetonitrile. Analogy to the nitroalkane anomaly

  1. Bernasconi, C.F.
  2. Sun, W.
  3. Garcia-Río, L.
  4. Yan, K.
  5. Kittredge, K.
Zeitschrift:
Journal of the American Chemical Society

ISSN: 0002-7863

Datum der Publikation: 1997

Ausgabe: 119

Nummer: 24

Seiten: 5583-5590

Art: Artikel

DOI: 10.1021/JA970193Z GOOGLE SCHOLAR