An Optimised Method to Synthesise N5O2 Aminophenols

  1. Oreiro-Martínez, Paula 1
  2. Corredoira-Vázquez, Julio 13
  3. Sanmartín-Matalobos, Jesús 12
  4. Fondo, Matilde 1
  1. 1 Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain
  2. 2 Institute of Materials (iMATUS), Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain
  3. 3 Phantom-g, CICECO—Aveiro Institute of Materials, Department of Physics, University of Aveiro, 3810-193 Aveiro, Portugal
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Actas:
ECSOC 2023 : The International Electronic Conference on Synthetic Organic Chemistry

Ano de publicación: 2023

Tipo: Achega congreso

DOI: 10.3390/ECSOC-27-16145 GOOGLE SCHOLAR lock_openAcceso aberto editor

Resumo

first_pagesettingsOrder Article ReprintsOpen AccessProceeding PaperAn Optimised Method to Synthesise N5O2 Aminophenols †by Paula Oreiro-Martínez 1,*ORCID,Julio Corredoira-Vázquez 1,2ORCID,Jesús Sanmartín-Matalobos 1,3ORCID andMatilde Fondo 1ORCID1Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain2Phantom-g, CICECO—Aveiro Institute of Materials, Department of Physics, University of Aveiro, 3810-193 Aveiro, Portugal3Institute of Materials (iMATUS), Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain*Author to whom correspondence should be addressed.†Presented at the 27th International Electronic Conference on Synthetic Organic Chemistry (ECSOC-27), 15–30 November 2023; Available online: https://ecsoc-27.sciforum.net/.Chem. Proc. 2023, 14(1), 17; https://doi.org/10.3390/ecsoc-27-16145Published: 15 November 2023Downloadkeyboard_arrow_down Browse Figures Versions NotesAbstractAminophenol compounds are usually employed in coordination chemistry due to their versatility to form metal complexes. Heptadentate N5O2 aminophenol ligands can lead to the formation of lanthanoid complexes with pentagonal bypiramidal (pbp) geometry, which are very interesting in the field of molecular magnetism. In this communication, we report an optimised method for obtaining two similar N5O2 aminophenols named 2-((((6-(((5-hydroxy-2-R-benzyl)(pyridin-2-ylmethyl)amino)methyl)pyridin-2-yl)methyl)(pyridin-2-ylmethyl)amino)methyl)-4-R-phenol (R = methyl or methoxy), which significantly improves the few examples of synthesis of this type of compound reported in the literature.

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