Synthesis of a Dysprosium(III) Complex with a Hexadentate Amine Ligand
- González-Barreira, Cristina 1
- Corredoira-Vázquez, Julio 12
- García-Deibe, Ana M. 1
- Fondo, Matilde 1
- 1 Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain
- 2 Phantom-g, CICECO—Aveiro Institute of Materials, Department of Physics, University of Aveiro, 3810-193 Aveiro, Portugal
Actas:
ECSOC 2023 : The 27th International Electronic Conference on Synthetic Organic Chemistry
Ano de publicación: 2023
Tipo: Achega congreso
Resumo
The use of polydentate macrocyclic Lewis bases is a way to contribute to determine the coordination number of metal complexes. In this way, hexadentate N6 donors can help to achieve lanthanoid complexes with coordination number 8. But the geometry of these complexes depends on the flexibility of the bases. In this way, in this communication we present the synthesis and crystallographic characterization of the dysprosium complex [DyLN6Cl2]Cl·2H2O, where LN6 is a flexible hexaaza donor.
Referencias bibliográficas
- Mitewa, (1994), Coord. Chem. Rev., 135–136, pp. 129, 10.1016/0010-8545(94)80067-7
- Rezaeivala, (2014), Coord. Chem. Rev., 280, pp. 203, 10.1016/j.ccr.2014.06.007
- Gavey, (2015), Coord. Chem. Rev., 296, pp. 125, 10.1016/j.ccr.2015.03.017
- Corredoira-Vázquez, J., González-Barreira, C., Oreiro-Martínez, P., García-Deibe, A.M., Sanmartín-Matalobos, J., and Fondo, M. (2023). Lanthanoid complexes of pentadentate and hexadentate N5 and N6 macrocycles: Synthesis and applications. J. Rare Earths, in press.
- Lamelas, (2016), Sens. Actuators B Chem., 225, pp. 481, 10.1016/j.snb.2015.11.090
- Lamelas, (2019), Polyhedron, 160, pp. 180, 10.1016/j.poly.2018.12.006
- Siemens Industrial Automation, Inc. (1996). SADABS: Area-Detector Absorption Correction, Siemens Industrial Automation, Inc.
- Sheldrick, (2015), Acta Cryst., A71, pp. 3
- Sheldrick, (2015), Acta Cryst., C71, pp. 3
- Llunell, M., Casanova, D., Cirera, J., Bofill, J.M., Alemany, P., Alvarez, S., Pinsky, M., and Avnir, D. (2005). SHAPE v1.1b, University of Barcelona.
- Casanova, (2008), Chem. Eur. J., 14, pp. 1291, 10.1002/chem.200701137
- Llunell, M., Casanova, D., Cirera, J., Alemany, P., and Alvarez, S. (2010). SHAPE: Program for the Stereochemical Analysis of Molecular Fragments by Means of Continuous Shape Measures and Associated Tools, University of Barcelona.