Dysprosium(III)-Mediated Carboxylate Formation from a Schiff Base
-
Corredoira-Vázquez, Julio
1
-
González-Barreira, Cristina
1
-
Deibe, Ana M. García
1
-
Sanmartín-Matalobos, Jesús
1
-
Fondo, Matilde
1
- 1 Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain
Konferenzberichte:
The 25th International Electronic Conference on Synthetic Organic Chemistry
Datum der Publikation: 2021
Art: Konferenz-Beitrag
Zusammenfassung
This work describes an uncommon new case of imine hydrolysis, leading to the formation of a carboxylate group. The conditions of the media that favor this conversion, which seem to be mediated by the presence of DyIII, are analyzed. The process brings about the formation of a dysprosium complex of formula {[(DyL2)2Na2(H2O)8][Et3NH]2[DyL2]2}·14H2O (1). Single X-ray characterization of the final product is reported.
Bibliographische Referenzen
- Reeves, (1965), J. Org. Chem., 9, pp. 3129, 10.1021/jo01020a061
- Fenton, (1994), J. Chem. Soc. Dalton Trans., 14, pp. 2213, 10.1039/dt9940002213
- Czaun, (2010), Inorg. Chim. Acta, 363, pp. 3102, 10.1016/j.ica.2010.05.025
- Barma, (2021), Eur. J. Inorg. Chem., 2021, pp. 2284, 10.1002/ejic.202100263
- Fondo, (2020), Dalton Trans., 49, pp. 8389, 10.1039/D0DT01293A
- Khatana, (2018), Synthesis, 50, pp. 4290, 10.1055/s-0037-1610069
- Dai, (2019), Org. Lett., 21, pp. 1393, 10.1021/acs.orglett.9b00101
- Yu, (2021), Lett. Org. Chem., 18, pp. 167, 10.2174/1570178617999200807210137
- Geissman, (1944), Org. React., 2, pp. 94
- Siemens Industrial Automation, Inc. (1996). SADABS: Area-Detector Absorption Correction, Siemens Industrial Automation, Inc.
- Sheldrick, (2015), Acta Cryst., A71, pp. 3
- Sheldrick, (2015), Acta Cryst., C71, pp. 3
- Fecteau, (2019), ACS Earth Space Chem., 3, pp. 170, 10.1021/acsearthspacechem.8b00130
- Llunell, M., Casanova, D., Cirera, J., Bofill, J.M., Alemany, P., Alvarez, S., Pinsky, M., and Avnir, D. (2005). SHAPE v1.1b, University of Barcelona.
- Casanova, (2008), Chem. Eur. J., 14, pp. 1291, 10.1002/chem.200701137
- Llunell, M., Casanova, D., Cirera, J., Alemany, P., and Alvarez, S. (2010). SHAPE: Program for the Stereochemical Analysis of Molecular Fragments by Means of Continuous Shape Measures and Associated Tools, University of Barcelona.