A convenient Pd-mediated oxidation of 4-methylbenzyl alcohol

  1. Sanmartín-Matalobos, Jesús 2
  2. Briones-Miguéns, Lucía 2
  3. García-Deibe, Ana 2
  4. Fondo, Matilde 2
  5. González-Bello, Concepcion 1
  1. 1 Centro Singular de Investigacion en Química Biológica y Materiales Moleculares (CIQUS), Universidad de Santiago de Compostela, Jenaro de la Fuente s/n, 15782 Santiago de Compostela, Spain.
  2. 2 Coordination and Supramolecular Chemistry Group (Suprametal), Institute of Materials (iMATUS), Department of Inorganic Chemistry, Faculty of Chemistry, Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, Spain
Actas:
Proceedings of The 17th International Electronic Conference on Synthetic Organic Chemistry

Ano de publicación: 2013

Tipo: Achega congreso

DOI: 10.3390/ECSOC-17-A012 GOOGLE SCHOLAR lock_openAcceso aberto editor

Resumo

A mild and convenient Pd-mediated aerobic oxidation of 4-methylbenzyl alcohol is described. We have applied the catalytic system Pd(OAc)2/Et3N to the oxidation of 4 methylbenzyl alcohol to 4-methylbenzyaldehyde. This method has resulted effective at room temperature without oxygen or air stream and without activated molecular sieves.