Different Bridging Preferences of Zinc and Palladium in Dimeric Complexes of a Ligand Based on 2-Tosylaminomethylaniline

  1. Sanmartín-Matalobos, Jesús 1
  2. Portela-García, Cristina 1
  3. Fondo, Matilde 1
  4. García-Deibe, Ana 1
  1. 1 Coordination and Supramolecular Chemistry Group (Suprametal), Institute of Materials (iMATUS), Department of Inorganic Chemistry, Faculty of Chemistry, Universidade de Santiago de Compostela, Avenida das Ciencias s/n, 15782 Santiago de Compostela, Spain
Actas:
Proceedings of The 18th International Electronic Conference on Synthetic Organic Chemistry

Ano de publicación: 2014

Tipo: Achega congreso

DOI: 10.3390/ECSOC-18-E005 WoS: WOS:000725553200013 GOOGLE SCHOLAR lock_openAcceso aberto editor

Resumo

We report here the formation of dimeric palladium(II) and zinc(II) complexes of a ligand (H2L) derived from the condensation of 2 tosylaminomethylaniline and 2,3-dihydroxybenzaldehyde.The structures in solution of the corresponding palladium(II) and zinc(II) complexes could be deduced from NMR studies. With the aim of establishing an energy-structure relationship between the two possible linkage isomers (μ-O bridged and μ-N bridged), some theoretical energy calculations have been performed.