Presence of toxic and hazardous substances in recycled rubber surfacesenvironmental distribution and toxicological implications

  1. Armada Álvarez, Daniel
Dirixida por:
  1. María Pilar Llompart Vizoso Director
  2. María Celeiro Montero Director

Universidade de defensa: Universidade de Santiago de Compostela

Ano de defensa: 2023

Tribunal:
  1. Enrique Roca Bordello Presidente
  2. Javier Hernández Borges Secretario/a
  3. Vera Homem Vogal
Departamento:
  1. Departamento de Química Analítica, Nutrición e Bromatoloxía

Tipo: Tese

Teseo: 790015 DIALNET

Resumo

This thesis focuses on the study of recycled tire rubber employed as infill in artificial turf football pitches or as flooring in children's playgrounds, among other uses. Different families of chemical compounds such as polycyclic aromatic hydrocarbons, plasticisers, antioxidants and vulcanisation additives were determined in different recycled tire rubber matrices. In addition, the diffusion of these substances into the environment (air and water) and the potential bioaccessibility via oral ingestion were studied. For this purpose, different analytical methodologies were developed and validated. Due to the wide variety of the studied samples, different simple and sustainable sample preparation techniques were employed prior to analysis by gas chromatography coupled to tandem mass spectrometry.