Photoreactivity and Novel Designs in Smart Chiral Material

  1. Francisco Rey Tarrío
Dirixida por:
  1. Emilio Quiñoá Cabana Director
  2. Félix Manuel Freire Iribarne Director

Universidade de defensa: Universidade de Santiago de Compostela

Fecha de defensa: 12 de decembro de 2022

Tribunal:
  1. Diego Peña Gil Presidente
  2. Alejandro Criado Fernández Secretario/a
  3. Ghislaine Vantomme Vogal
Departamento:
  1. Departamento de Química Orgánica

Tipo: Tese

Teseo: 770017 DIALNET lock_openMINERVA editor

Resumo

Helical polymers, covalent and supramolecular, have attracted the attention of the scientific community for the relation structure/function found in helical biomacromolecules such as peptides, proteins, DNA. Inspired by these works, in this thesis photochemical properties of several synthetic helical polymers from poly(phenylacetylene)s were studied, and the results were applied to elucidate its secondary structure. Furthermore, new helical systems, covalent and supramolecular were prepared and studied, resulting in novel multi-responsive and multi-helical materials.