Catalizadores de níquel y paladio con ligandos carbeno N-heterocíclicos para la formación de enlaces C-C y C-N

  1. GONZÁLEZ RULL, SILVIA
Supervised by:
  1. Manuel Romero Fructos-Vázquez Director
  2. Tomás Rodríguez Belderraín Director

Defence university: Universidad de Huelva

Fecha de defensa: 15 June 2017

Committee:
  1. José Luis Mascareñas Cid Chair
  2. Ana Carmen Albéniz Jiménez Secretary
  3. Beatriz Royo Cantabrana Committee member

Type: Thesis

Abstract

This PhD Thesis is divided in three Chapters. Two of them are focused on the use of nickel and palladium complexes with N-heterocyclic carbene ligands (NHC) and phosphine-functionalized N-heterocyclic carbene ligands (NHCP), in the cross-coupling reactions to form C~C and C-N bonds. The third Chapter describes the cyclopropanation reaction of styrene with different diazocompounds catalyzed by nickel and palladium complexes with NHCP ligands.