Thermoelectric Properties of SrTiO3 and CaTiO3 Thin Films 

  1. Sarantopoulos, Alexandros
unter der Leitung von:
  1. Francisco Rivadulla Fernández Doktorvater

Universität der Verteidigung: Universidade de Santiago de Compostela

Fecha de defensa: 17 von Januar von 2019

Gericht:
  1. Luis Morellón Alquézar Präsident/in
  2. Víctor Pardo Castro Sekretär
  3. Jonathan Malen Vocal
Fachbereiche:
  1. Departamento de Química Física

Art: Dissertation

Zusammenfassung

This thesis studies the thermoelectric properties of SrTiO3 and CaTiO3 thin films. We study the effects of epitaxial strain and incorporated anionic/cationic defects on the functional properties of the thin films. Controlling the parameters during the fabrication process, determines the structural properties of the thin films, which permits the tailoring of the magnetotransport and thermoelectric properties of the thin films. We discuss the similarities in the behaviors observed in our thin films, to the ones reported in LaAlO3/SrTiO3, and other interfaces. We report a dramatic decrease in the thermal conductivity of the thin films due to epitaxial strain, point defects, and ferroelectricity. Moreover, we have observed that oxygen vacancy manipulation in CaTiO3 thin films reveals a ferroelectric-like response.